Haloalkanes and Haloarenes

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πŸ“š Key Concepts

  • Classification
    • Primary, secondary, tertiary haloalkanes
    • Aromatic halides
    • Mono, di, trihalogen compounds
  • C-X Bond Nature
    • Polarity
    • Bond strength
    • Bond length variations
  • Preparation Methods
    • From alcohols
    • From hydrocarbons
    • From alkenes
    • Sandmeyer reaction
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    🎯 Key Formulas

  • R-OH + HX β†’ R-X + Hβ‚‚O
  • R-OH + SOClβ‚‚ β†’ R-Cl + SOβ‚‚ + HCl
  • ArN₂⁺Cl⁻ + CuX β†’ ArX + Nβ‚‚ + CuCl
  • Finkelstein reaction: R-Cl + NaI β†’ R-I + NaCl
  • Swarts reaction: R-Cl + AgF β†’ R-F + AgCl
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    ⚠️ Common Mistakes to Avoid

  • Incorrect nomenclature
  • Misunderstanding reaction mechanisms
  • Confusing SN1 and SN2 reactions
  • Overlooking stereochemistry
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    πŸ“– Knowledge Prerequisites

  • Organic chemistry basics
  • Bonding types
  • Reaction mechanisms
  • Stereochemistry
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    πŸ’‘ Tips for Students

  • Learn IUPAC nomenclature
  • Understand reaction mechanisms
  • Practice stereochemical representations
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    πŸ‘‰ Practice Recommedations

  • Solve reaction mechanism problems
  • Draw structural representations
  • Compare reaction characteristics
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